課程資訊
課程名稱
高等物理化學一
Advanced Physical Chemistry (Ⅰ) (Chem. Thermodynamics)(Ⅰ) 
開課學期
110-1 
授課對象
理學院  化學所化學組  
授課教師
鄭原忠 
課號
Chem7031 
課程識別碼
223EM1310 
班次
 
學分
3.0 
全/半年
半年 
必/選修
必修 
上課時間
星期二6,7(13:20~15:10)星期四2(9:10~10:00) 
上課地點
化210室化210室 
備註
本課程以英語授課。本班英文授課。
限碩士班以上 且 限本系所學生(含輔系、雙修生)
總人數上限:30人 
 
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課程概述

This course covers the principles and methods of equilibrium statistical mechanics for applications to chemical physics problems. The lectures will be divided into three parts: a short review of thermodynamics principles, the concepts of ensemble theory and the applications to gas, liquid, solution and solid systems. The final part will introduce the phase transition and the theory of Brownian motion.

Planned topics: laws of thermodynamics, thermal equilibrium and temperature, ensemble theory, entropy, non-interacting systems (gas and solid), chemical equilibrium, imperfect gases, classical liquids, ionic and non-ionic solutions, Ising models. Langevin equation and Brownian motion. 

課程目標
This course aims to introduce basic concepts of equilibrium statistical mechanics for physical chemistry in the graduate level. 
課程要求
待補 
預期每週課後學習時數
 
Office Hours
 
指定閱讀
 
參考書目
Textbooks:

Introduction to Modern Statistical Mechanics, David Chandler, Oxford University Press.

Statistical Physics of Particles, Tehran Kardar, Cambridge University Press.

References:

Statistical Mechanics, Donald Allan McQuarrie, University Science Books; 2nd edition. 
評量方式
(僅供參考)
   
課程進度
週次
日期
單元主題
Week 1
9/23  Notions of statistical thermodynamics 
Week 2
9/28, 9/30  Laws of thermodynamics, Fundamental equations of thermodynamics 
Week 3
10/5, 10/7  Equilibrium and stability, Statistical methods and ensemble 
Week 4
10/12, 10/14  The canonical ensemble, Entropy and free energy functions 
Week 5
10/19, 10/21  Photon gas, harmonic oscillators 
Week 6
10/26, 10/28  10/26: Mid-term Exam
10/28: Statistics of particles 
Week 7
11/2, 11/4  Ideal polyatomic gas 
Week 8
11/9, 11/11  Chemical equilibrium 
Week 9
11/2, 11/4  Ising model, Phase transitions 
Week 10
11/23, 11/25  Imperfect gas 
Week 11
11/30, 12/2  Liquid theory 
Week 12
12/7, 12/9  Electrolytes 
Week 13
12/14, 12/16  Brownian motion 
Week 14
12/21  Final Exam